Okay, seeings how I assume this is a image link let's get down to buisness
the CSS code:
Code:
a {
background: url("http://image.com/image/image.jpg");
/*then the rest of course*/
}
a:hover {
background: url("http://image.com/image/otherimage.jpg");
}
Then of course
Code:
<a href="index.php">Home</a>
Now this is untested, and can't be used in certain cases. But this can easily be modified to work to your needs

This is meant to get you on a start. For more indepth look at all this I'd recommend
www.w3schools.com